Thursday, November 28, 2019
Andrew Jacksons Impeachment essays
Andrew Jacksons Impeachment essays With the assassination of Lincoln, the presidency fell upon an old-fashioned southerner named Andrew Johnson. Although an honest and honorable man, Andrew Johnson was one of the most unfortunate Presidents. Over time there has been a controversial debate as to whether Johnson deserved to be impeached, or if it was an unconstitutional attempt by Congress to infringe upon the presidents authority. The impeachment of Andrew Johnson was politically motivated. The spirit of the Jacksonian democracy inspired Andrew Johnson. From this influence he helped found the Democratic Party in his region and became elected to the town council in 1829. After serving in his town council for two years he was elected mayor in 1831. Johnson was a strict constructionist and an advocate of states' rights who distrusted the power of government at all levels. Following his term as Mayor Johnson won elections to the Tennessee State legislature in 1835, 1839, and 1841. After serving these terms he was elected t o Congress in 1843. As a member of the US House, Johnson opposed government involvement in the nations economy through tariffs and internal improvements. "In 1852 Johnson lost his seat in the US House because of gerrymandering by the Whig- dominated state legislature." (Jackson) Following his loss he came back in 1853 to win a narrow victory for governor and served two terms. In 1857, Johnson was then elected to represent Tennessee in the US Senate. "While serving in the Senate Johnson became an advocate of the Homestead Bill, which was opposed by most Southern Democrats and their slave owning, plantation constituents." (Kennedy) This issue strained the already tense relations between Johnson and the wealthy planters in western Tennessee. Eventually the party split into regional factions. Johnson made the decision to back the Southern Democratic nominee, John Breckinridge. By this time the rupture between Johnson and most Southern Democrats was too deep to ...
Sunday, November 24, 2019
Free Essays on The Demon Lover
During times of war, ââ¬Å"people [are] often led down strange paths in search of indestructible landmarks in a destructible worldâ⬠(Mitchell 44). Hallucinations provide such landmarks in extreme moments. Paranoia appears to those who encounter the intense emotions of war. The psychological shocks of war deprive and fray emotions. Pressures from a previous war threaten uncertainties and fears. In ââ¬Å"The Demon Lover,â⬠Elizabeth Bowen reflects how war can take revenge on a personââ¬â¢s emotions through her use of setting and characterization. In ââ¬Å"The Demon Loverâ⬠, Bowenââ¬â¢s use of setting exemplifies that war can take revenge on a personââ¬â¢s emotions. While walking up to Kathleen Droverââ¬â¢s old home, ââ¬Å"an unfamiliar queernessâ⬠fills her from the inside out (346). The visit home in which she experiences war, unsettles her. Memories of war escalate inside her. For Mrs. Drover, already prone to a sense of loss, ââ¬Å"the return to the house is a shattering revelation, a threshold experience that activates her dormant hysteriaâ⬠which brews inside her after all these years (Hughes 52). As Kathleen nudges her front door open, ââ¬Å"dead airâ⬠greets her with remembrance of her past feelings (346). A ghost-like presence overwhelms Mrs. Drover, which ignites wartime emotions. The aged residence suggests the consciousness of time and the company of death. ââ¬Å"The hollowness of the house . . . cancelledâ⬠many memories that Kathleen bears in her mind from her youth (350). Voices, ways of life, warmth and love fill her home until war rips it apart. The uninviting existence of her surroundings produces her present condition of madness. Mrs. Drover comprehends that down in the basement ââ¬Å"a door or window was being opened by someoneâ⬠to cause the draught that hits her face while she stands at the top of the staircase (351). The intensity of what Kathleen feels and experiences is as real as the war she experienced. ââ¬Å"Through th... Free Essays on The Demon Lover Free Essays on The Demon Lover During times of war, ââ¬Å"people [are] often led down strange paths in search of indestructible landmarks in a destructible worldâ⬠(Mitchell 44). Hallucinations provide such landmarks in extreme moments. Paranoia appears to those who encounter the intense emotions of war. The psychological shocks of war deprive and fray emotions. Pressures from a previous war threaten uncertainties and fears. In ââ¬Å"The Demon Lover,â⬠Elizabeth Bowen reflects how war can take revenge on a personââ¬â¢s emotions through her use of setting and characterization. In ââ¬Å"The Demon Loverâ⬠, Bowenââ¬â¢s use of setting exemplifies that war can take revenge on a personââ¬â¢s emotions. While walking up to Kathleen Droverââ¬â¢s old home, ââ¬Å"an unfamiliar queernessâ⬠fills her from the inside out (346). The visit home in which she experiences war, unsettles her. Memories of war escalate inside her. For Mrs. Drover, already prone to a sense of loss, ââ¬Å"the return to the house is a shattering revelation, a threshold experience that activates her dormant hysteriaâ⬠which brews inside her after all these years (Hughes 52). As Kathleen nudges her front door open, ââ¬Å"dead airâ⬠greets her with remembrance of her past feelings (346). A ghost-like presence overwhelms Mrs. Drover, which ignites wartime emotions. The aged residence suggests the consciousness of time and the company of death. ââ¬Å"The hollowness of the house . . . cancelledâ⬠many memories that Kathleen bears in her mind from her youth (350). Voices, ways of life, warmth and love fill her home until war rips it apart. The uninviting existence of her surroundings produces her present condition of madness. Mrs. Drover comprehends that down in the basement ââ¬Å"a door or window was being opened by someoneâ⬠to cause the draught that hits her face while she stands at the top of the staircase (351). The intensity of what Kathleen feels and experiences is as real as the war she experienced. ââ¬Å"Through th... Free Essays on The Demon Lover In the short story,â⬠The Demon Loverâ⬠, by Elizabeth Bowen, Mrs. Drover has made a pact with the devil {claim statement}. Nineteen year-old Kathleen (Mrs. Drover) is engaged to a man who is about to leave for war {background}. Oddly enough, he is not very receptive to her emotionally and actually, is rather frigid acting towards the young girl whom he is supposed to marry. Actually, it seems to be more of a business relationship than a bond created out of love. There are many ways that Elizabeth Bowen proves to the reader that Mrs. Drover has made a pact with the devil {warrant}. By making a pact with the devil I mean, surrendering blood as part of an oath to Satan, trading oneââ¬â¢s soul for a favor for a specified number of years and/or accepting the Devils mark {definition}. Upon entering the house, an eerie feeling hangs in the air. Bowen makes this known by describing the atmosphere and feelings that are felt by Mrs. Drover as she walks into the old house. For example, nobody knows that she is coming to town; yet, as she enters the dark, cold room her eyes fall to a fresh letter placed on a dusty table by the door. The date on the letter is the present day, no return address can be found, and there is no stamp, which proves that the letter has not gone through the mail. As Kathleen opens the letter, Bowen makes it clear that the Devil has returned to make sure that the promise, made 25 years ago, by the young girl and the face-less man is honored. The meaning of the pact made in ââ¬Å"The Demon Loverâ⬠can be interpreted in many different ways. For instance, one point of view in this matter is that the Devil promises Kathleen that she will marry and bear children in a time when men are scarce due to the war, and she, in return, will join him in 25 years. In times of war, women are abundant and men are extremely scarce for the obvious reason. In 1916, when this story takes place, women do not have many choices concerni... Free Essays on The Demon Lover ââ¬Å"The Demon Lover,â⬠by Elizabeth Bowen, is a story about Kathleen Drover and a promise that she makes twenty-five years before. Kathleen goes to her old house in order to collect a few belongings, and she finds a letter inside the house with her name on it. It discusses an arranged meeting between herself and someone whom she shares an ââ¬Å"anniversaryâ⬠with. She begins to think, all the while becoming more and more cautious and afraid. She becomes frantic, and plans to leave the house and find a taxi so that she can return to the house and take the driver inside with her, so that she can collect the items that she needs. When she finds a taxi, she sits in the back seat, only to discover that the driver of the car is the man she is trying to escape from. He drives off ââ¬Å"into the hinterland of deserted streets.â⬠The central idea is that when people make promises, escaping from those promises is not always possible. Kathleen is obviously a naà ¯ve girl when she is younger. She meets a man who pays attention to her, and she becomes fixated with him. He makes her promise to wait for him, and he has her make a blood promise by cutting the palm of her hand with one of his military buttons. After this encounter, she tries to forget about her promise, and she tries to escape her fate. She even represses the memory of what he looks like, and the details of her promise. A dynamic character, she is strong and brave when she enters the old house, but by the end, her fear gets the best of her and she panics. By becoming panicked, she plays right into his hands. The conflict in the story is between honoring commitments and breaking them in an effort to change the past, and it is an internal conflict. The man in this story symbolizes the devil, and Kathleen makes an agreement with him in blood that she will wait for him, and be with him in twenty-five years. In the meantime, she gets married and has children because she believe...
Thursday, November 21, 2019
Annoted Bibliography on STIs Literature review Example | Topics and Well Written Essays - 2500 words
Annoted Bibliography on STIs - Literature review Example In this important countrywide rule document, sexual health remains termed as one of six vital considerations, and the HDA prove summarizations chosen like the origin of data on efficient interventions. During 2005, DH compiled the action arrangement Delivering selecting health, which fixes vital aims around STIs, rolling out Chlamydia screening and access to genitourinary medicine (GUM) clinics inside 48 hours. During 2005, the HDA merged with the National Institute for Clinical Excellence (NICE), to make the current National Institute of Health and Clinical Excellence and maintained the short form NICE (Masters, 2013:194). The latest institution progresses with the dedication to construct on the proof foundation in public health. In the process of the Stateââ¬â¢s progressive dedication to sexual health and HIV, and the need to base STI control in precise proof, it remained seen important to review the 2004 Evidence Briefing to make sure that the major current update stage proof r emains accessible for arranging services and increasing the sexual health of the people. NICE proof briefings account on reviews of reviews, rarely termed to as tertiary stage study. They constitute contextual descriptions of the advantages and disadvantages of the proof from reviews, spotting of loopholes in the proof, a breakdown of forthcoming major and minor study requirements, and a debate of the effects of the proof for rule and practice (Peate, 2010:6). Summary Article 1: Policy During 2001, the DH authored the initial National Strategy for Sexual Health and HIV. This established five major purposes, together with minimizing the spread of STIs with a countrywide objective of a 25% minimization in lately gonorrhea diseases by 2007, thus lowering dominance of undiagnosed STIs and lowering disgrace related with STIs. In addition, after this, the white paper Choosing Health: making healthy choices easier, constituted sexual wellbeing as one of its main privileges. This has motiva ted a re-energized dedication to deal with sexual disease health, and extra materials have remained offered for acting as such. In the doing arrangement, the State stipulated its goals to increase sexual health services in a latest $300m schedule for the coming three years (Carroll, 2004:340). Article 2: Epidemiology The examination of STIs depends on GUM clinicians accounting for increased figures of chosen states by gender and age, and for a few states, if matters in men are heterosexual of from intercourse between men. These remain delivered quarterly on KC60 forms. Whereas there exists disadvantages of the scheme, it is a precise origin of information on behaviors. Further contextual data remains looked for from extra studies, like the Gonococcal Resistance to Antimicrobials Surveillance Programme (GRASP) study to examine objection to gonorrhea cure and facilitated examination of occurrences of before exceptional diseases like syphilis and lymphogranuloma Venereum (LGV). There a re recently two current vaccines under review, both of which focus to cover versus the two mini-kinds that lead to warts. Detectives of genital warts rose by 3.1% between 2005 and 2006. During 2005, 50% of detectives remained in heterosexual men, 47% in females, and 3% in men who have intercourse with men (MSM)
Wednesday, November 20, 2019
STRATEGIC CHANGE MANAGEMENT NHS Essay Example | Topics and Well Written Essays - 3000 words
STRATEGIC CHANGE MANAGEMENT NHS - Essay Example Reference should be primarily made to the ââ¬Ëimprovisational approachââ¬â¢ (Smit 2000, p.1995) of strategic change. The above theory is used in a particular phase of change management: the implementation phase. The theory, which has been developed by ââ¬ËRedding and Catalanello in 1994ââ¬â¢ (Smit 2000, p.1995) has three, key, characteristics: a) it emphasizes on experimentation, b) it promotes sanctions rather than direct interventions and c) it is based on the transformation of existing structures and the rewarding of individuals for supporting change (Smit 2000). Through a different point of view, the Open Systems theory promotes the idea that ââ¬Ëall organizations are members of an open systemââ¬â¢ (Wilson 1992, p.42). ... One of the most known models of change is that developed by Lewin in 1950 (Kew and Stredwick 2005). The specific model which is presented in Figure 1, below, promotes the idea that in all organizations change is implemented in three phases: ââ¬Ëunfreezing, movement and refreezingââ¬â¢ (Kew and Stredwick 2005, p.221). These phases could be analyzed as follows: a) unfreezing; before change is attempted it is required that awareness of the need for change exists; this phase of Lewinââ¬â¢s model reflects the realization of the need for change, b) movement; the particular phase refers to the actions taken for promoting change; these actions can be differentiate across organizations according to organizational goals, the market conditions and the resources available and c) refreezing; this phase of Lewinââ¬â¢s model shows the transition to a new organizational environment, after the implementation of change has been completed ((Kew and Stredwick 2005). Figure 1 ââ¬â Lewinâ â¬â¢s model of change management (source: http://www.web-books.com/eLibrary/NC/B0/B58/047MB58.html) Another approach for explaining organizational change is described in the study of Glynn and Woodside (2012). The above researchers refer to the model of strategic change developed by Barr and Huff in 1997. According to the particular model managers are likely to promote changes only in the following case: if changes have already appeared in the firmââ¬â¢s environment then measures are taken so that the organization is able to respond to these changes (Glynn and Woodside 2012). In other words, in the context of each organization changes can lead to further changes, either in the short or the long term. However, managers do not always respond
Monday, November 18, 2019
Explorer Essay Example | Topics and Well Written Essays - 500 words
Explorer - Essay Example Little did we know that this peculiar personality of his could be a problem solver and even a life-saver. This happened when we went hiking. We used to do an overnight hiking and do camp outs in the forest. We already know the routine of what to bring during a camping. The tent, blankets, insect repeller, even first aid kit were almost always ready for us to bring as a logistical support. For food, we bring ready to open canned goods because of its convenience. Except this once instance where one of my brilliant cousin did the grocery and chose to buy canned goods which does not have the automatic opener (the protruding level like thing that we just have to pull to open the can). Now we are the camping site, miles away from home and in a middle of a night, starving and we are presented with a problem: how can we eat our canned goods when there is no opener. No one also brought a can opener because we are used to the idea that canned goods has its own opener. It was a problem solving situation. Our uncle threw the problem to us for us to find a solution. The solutions that were presented ranged from anecdotal to ridiculous to irritating. A cousin proposed that we skip the dinner for the night as a means to fast. I was hungry and so are other cousins so nobody agreed with his idea. Another bright idea from a cousin who could put us all in danger was putting the canned goods in fire hoping that the heat inside will open the can itself. We are worried however that it might explode or we might just render the food inedible by setting the can on fire. Another idea that was suggested was to smash the can so that it will open. For sure it will open only that we also cannot eat its contents. Until Jim made his typical smirk which we already know he is into something. He brought out his fork and put it on the lid of the canned good (it was spam, I think). Then Mark get it, he immediately jump out of seat and used
Friday, November 15, 2019
EHR Implementation Issues
EHR Implementation Issues Melchor Abejon Any adverse event that obstructs the development and success of an organization should be investigated to discover and understand the initiating cause of such event and to consequently establish corrective actions to prevent its recurrence in the future. This paper intends to: Identify the approach to be taken to address the reporting problem at Western Heights Hospital (WHH). To create a flowchart outlining the process to be taken in finding a solution to the organizations reporting problem. Approach to Address the Reporting Problem at Western Heights Hospital As stated in the given scenario, the WHH is unable to report on various state and federally mandated quality measures. Definitely, this problem needs immediate attention as this process is essential to the organization to improve and maintain quality. As the clinical content manager and leader of all reporting efforts in the organization, it is my primary concern to address and find solution to the problem. My approach would be to perform a Root Cause Analysis (RCA). Conducting an RCA would help me discover and understand the initiating cause or causes of the problem and to develop corrective actions to prevent its recurrence in the future. Root Cause Analysis Below is a flowchart showing my steps to performing an RCA for the problem. Identify the problem Charter and appoint team facilitator and members à Describe the incident Identify the contributing factors Identify the root cause or causes Eliminate the root cause or causes Evaluate and measure Identify the problem. This step will include determining the problem to be investigated. The problem statement from the scenario would be, The organization is unable to report on various state and federally mandated quality measures. Also, included in this step is to gather preliminary information about the problem which can be discussed later by my team. Charter and appoint a team facilitator and members of the team.Ãâà In this step, a team facilitator will be designated who will work with the leadership to launch a project charter that will guide the team in managing the scope of the project and in implementing changes that are linked to the root causes identified in the RCA process. Also, team members will be selected who are familiar with the systems and processes involved in the problem. Describe the incident. In this step, facts surrounding the problem will be collected and organized, on why the organization fails to do quality reporting measures. The preliminary information gathered in step 1 will be shared and discussed with the team. Identify contributing factors.Ãâà The knowledge gained in step 3 will be used to dig deeper into what happened and why it happened. Also in this step, the conditions, circumstances and situations that caused the organization not to be able to report will be identified. A thorough investigation of the organizations current data systems and the processes from patient data capture to electronic reporting will be carried out to determine any lacking or faulty process that have resulted to the incomplete generation of data. Identify the root causes. The contributing factors will be examined to find the root cause of the problem. In the given scenario, there could be many underlying reasons that had caused the organizations failure to report. Contributing factors could be due to (a) incomplete data as mentioned, (b) failure of systems to communicate, (c) poor data quality, (d) lack of data standards. These contributing factors are interrelated to each other to significantly affect the interoperability of systems. Identifying the root cause should be dug deeper by asking repeated why questions of the contributing factors. Eliminate the root causes. This step will also include the design and implementation of changes to eliminate the root cause and to reduce and or prevent the recurrence of the same event in the future. If there are multiple root causes, there will be corrective actions to address each root cause. In the given scenario, the failure to report could probably be due to lack of interoperability or failure of systems to communicate due to poor data quality as manifested by incomplete data generated by the organizations system. This problem could be addressed by improving patient data capture and by developing an efficient data dictionary. Data integration would probably be needed to cleanse all dirty data, and as well as to employ data standards to improve clinical documentation,Ãâà and data interchange standards to enable the systems to achieve full interoperability and be able to exchange and integrate data among healthcare applications in a state , regional and nationwide level. Evaluate and measure. In this step, the success or improvement of actions will be evaluated and measured and will be monitored overtime. Reference Center for Medicare and Medicaid Services (CMS) (n.d.). Guidance for performing root cause analysis (RCA) with performance improvement projects.Ãâà Retrieved February 20, 2017 from https://www.cms.gov/medicare/provider-enrollment-and-certification/qapi/downloads/guidanceforrca.pdf
Wednesday, November 13, 2019
American Imperialism Essay -- Nongovernmental Oganizations
To use the title ââ¬ËTransnational Americanââ¬â¢ (Grewal, 2005) might be more politically correct than American imperialism but I contend that one is in fact an agent of the other. The two readings for this week converge around the discussion of transnationalism and neoliberalism although in slightly different ways. Grewal (2005) discusses transnationalism in relation to the United States and its cultural, social, political and economic influence on other nation-states specifically through technologies, biopolitics and geopolitics. Grewal presents interesting arguments to support the view that the construction of human rights activism since the 1960ââ¬â¢s was a geopolitical strategy used by the United States to extend its imperialist grasp on the outside world. Grewal (2005) posits that the development of the feminist and womenââ¬â¢s rights movements were born out of human rights discourse that quickly became ââ¬Å"transnational instruments of technologies of governmenta lity, creating and applying knowledges and techniques that promote welfare and security, rather than just the rights of populationsâ⬠(Grewal 2005:122). The birth of Nongovernmental Organization (NGO) came out of a desire to ââ¬Å"move women [vulnerable populations] from the margins to the center by questioning the most fundamental concepts of our social order so that they take better account of womenââ¬â¢s livesâ⬠(Grewal 2005:126). In the process human rights issues became wedded to womenââ¬â¢s rights, social justice and later on to development. NGOs at the time of its inception were seen as politically autonomous entity that would intervene ââ¬Å"to ensure the welfare of female populations, the inefficiency of the state, and its ideology of patriarchyâ⬠(Grewal 2005:127). But cultural, socio-political... ...loitation, the US maintains its embargo on Cuba and continues to police movements across its borders; only the future knows how the current anti-immigration sentiments might unfold and materialize. Space does not permit an elaborate discussion about the politics of the United Nations, the World Bank or the IMF, but as a parenthetical note, these are also examples of an imperial or should I say transnational apparatuses taken advantage of the by the United States. In the final analysis, I concur with Comaroff and Comaroff (2001) that ââ¬Å"relationship between the nation-state and millennial capitalismâ⬠¦is not synonymous with globalism, although globalization is and inherent part of itâ⬠but I would add more specifically that globalization like its predecessor colonalization, imperialization and now neoliberalism is a capitalist apparatus (Comaroff & Comaroff, 2001:34)
Sunday, November 10, 2019
Isolation of Crude Acetaminophen Essay
After first isolation of crude acetaminophen, 1.22g of light, brown shiny, fine Crestline solid emulated, which demonstrated slight less than 0.030g of product was lost from original 0.150g of p-aminophenol. The melting point range of crude acetaminophen ranged from 166.8-167.6à °C, when compare to the known melting point of pure acetaminophen which ranged from 169.5-171à °C, is slightly depressed. After decolonization of crude acetaminophen 0.060g of a very light tan/pink almost white, fine, shiny crystalline purified acetaminophen was recovered. Significant amount was lost; slightly over half was lost from 0.122g crude acetaminophen. Purified acetaminophen resulted in a much lighter coloration than the crude acetaminophen. Purified acetaminophen was slightly light tan/pink nearly white, whereas crude acetaminophen was light brown. After crystallization of acetaminophen, 0.028g of whiter, shiny, fine crystals resulted with no apparent odor. Slightly less than half of product was l ost from 0.060g purified acetaminophen that was crystallized and about 0.122g was lost from the original 0.150g of p-aminophenol started with. The melting point range of the crystallized acetaminophen (166.1-169.8 à °C when compared to the known melting point range of pure acetaminophen at 169.5-171à °C is clearly depressed and elongated. 169.5-171à °C Calculations: % yield of crude product: x = 0.207g crude acetaminophen x 100 = 58.7% % yield of crystallized (final) product x = 0.207g crude acetaminophen x 100 = 13.5% Observations: Weigh out about 0.150g p-aminophenol and place this in a %ml conical vial. Note: some amount of product was lost do to spillage. .150g weighted out; p-aminophenol is a dark purple powder containing few small grains. Using pipette, add 0.450ml of water and 0.165ml of acetic anhydride. About 450ml and 0.165ml of water and acetic anhydride weighted out. Addition of water formed dark purple viscous mixture; most p-aminophenol dissolved. Addition of acetic anhydride to the mixture produced a dark brown mixture brown precipitate seemed to have formed at the bottom of the vial. Heat the reaction with an alumina block at about 120à °C while stirring gently. After solid precipitate has completely dissolved heat for an addition 20 minutes. Remove vial from heat and allow cooling. Once cool remove the spin vane and air condenser from the conical vial and let cool to room temperature. Once safe to touch put the mixture in an ice bath for 15-20 minutes allowing for crystallization. Collect crystals through vacuuming through Hirsch funnel for 5-10 minutes allowing for air to go through. Once dry add weight the crude product and do melting point range test 166.8-167.6à °C compared to the know melting point range of 169.5-171à °C. Dissolve 0.2g of sodium Dithionite in 1.5ml of water in a 5ml conical vial. Weight out about 0.204g of sodium dithionite, a grey- white solid powder, add the crude product to the vial and heat up the mixture at about 100à °C for 15 minutes. After heating the crude product completely dissolved producing a light tan translucent solution. Note: spillage occurred when transferring crude product into conical vial. Cool mixture in an ice bath for about 10 minutes. Collection of crystals are done by vacuuming with the Hirsch funnel, once dry weight the purified acetaminophen 0.060g resulted. The purified acetaminophen resulted in a much lighter coloration than the crude. Place purified acetaminophen in a craig tube. Crystallize the material from a solvent mixture composed of 50% water 50% methanol by volume. Set up the Craig tube apparatus described in technique 11, section11.4. Add drops of hot solvent until solid is dissolved. When product has dissolved, place the Craig tubeà into a 10ml Erlenmeyer flask, insert the inner plug of the Craig tube and allow solution to cool. Place in ice bath for several minutes to allow acetaminophen to crystallize. After crystallization has occurred collect crystals using apparatus shown in technique 8 figure 8.11, place assembly in centrifuge for several minutes collect crystals on watch glass weight it at 0.028g and find the melting point range of 166.1-169.8à °C. Questions: 1. Most compounds have lower solubilityââ¬â¢s at lower temperatures. You can obtain more product y crystallization at lower temperature. 3. Product can be lost through Hirsch funnel if over washed. 4. x = 0..180g crude acetaminophen x = 0.00119g mol acetaminophen 6. Discussion: Through the main reaction between 0.150g of p-aminophenol with acetic anhydride, 0.122g of crude acetaminophen was produced along with some acetic acid. This indicates a 58.7 percent yield of crude acetaminophen. This is a fair percent yield considering a slight amount of p-aminophenol was lost due to spillage in the transferring process into conical vail and slight amount of crude acetaminophen was lost when trying to remove crystallized crude acetaminophen from conical vial. Percent yield is 58.7% indicating loss of reactants or spillage of products. There is possible error when performing suction filtration; too much washing of product can cause product to fall through filter ultimately decreasing overall percent yield. also overheating may have caused a loss of product; some of the product may have been splattered out of the reaction vessel when heating. 1005 yield would mean that one has carried out the lab activities perfectly producing the predicted amount of product. Given the 58.7% yield actually obtained, it is evident that experimental procedures be accurately followed for further improvement. It is in the transferring process ofà p-aminophenol to a 5mL conical vial. Where error is most critical and product can be readily lost. After decolorization process, 0.060g of decolorized/purified acetaminophen was obtained indicating a significant loss of product. Prior to decolorization process, 0.122g of crude acetaminophen solid was present, meaning half of product was lost in the decolorization process. It is important to note that a significant amount of product was lost due to spillage when transferring crude acetaminophen into conical vial to decolorization. Error may also be present if mixture is overheated and product is evaporated off. After crystallization process of purified acetaminophen, 0.028g of white final acetaminophen resulted indicating a 13.5% yield. this is a poor percent yield. this indicates slightly less than half of 0.060g of purified acetaminophen was lost. Such a low percent yield can be attributed to the loss of product throughout the crystallization process. It is important o note that a significant amount of product was lost within supernatant after centrifugation, also, product was lost when trying to remove product from Craig tube and plug. Purity of final product of acetaminophen was tested through qualitative observation of coloration and by comparing obtained melting point ranges of crude and final acetaminophen to the literature melting point range of pure acetaminophen. Because crude solid acetaminophen contains dark impurities carried along with p-aminophenol we can qualitatively compare the level of impurity before and after decolorization. As for the second test for impurity, the melting point range of the crude acetaminophen, 166.8-167.6à °C is slightly depressed when compared to the known melting point range of pure acetaminophen 169.5-171à °C. Crude acetaminophen melting point range is depressed by 2.7à °C. A difference of less than 5à °C indicates a good melting point range was obtained for crude acetaminophen this indicating a minimal amount of impurity present. The melting point range of final crystallized acetaminophen, 166.1-169.8à °C is slightly depressed and elongated when compared to the known me lting point range of pure acetaminophen 169.5-171à °C. It is depressed by 3.4à °C and elongated by 2.2à °C. A difference of less than 5à °C indicates a good melting point range was obtained, though impurities may still be present. When crystals are isolated by filtration from a solvent, it is important to allow complete drying/evaporation of the solvent in order to minimize impurities and get a good melting range. Residual solvent may also function as an impurity and will depress/broaden the melting range for acetaminophen. When two chemicals are mixed, side reactions may take place and produce by-products which can serve as impurities ultimately lowering and elongating the melting point range. For further reference, one must meticulously carry out experimental procedures to ensure that neither reactants nor product is lost and higher percent yield is obtained.
Friday, November 8, 2019
Understanding Jim Crow Laws
Understanding Jim Crow Laws Jim Crow laws maintained racial segregation in the South beginning in the late 1800s. After slavery ended, many whites feared theà freedomà blacks had. They loathed the idea that it would be possible for African Americans to achieve the same social status as whites if given the same access to employment, healthcare,à housing ,à and education. Already uncomfortable with the gains some blacks made duringà Reconstruction, whites took issue with such a prospect. As a result, states began to pass laws that placed a number of restrictions on blacks. Collectively, these laws limited black advancement and ultimately gave blacks the status of second-class citizens. The Origins of Jim Crow Florida became the first state to pass such laws, according to Americas History, Volume 2: Since 1865.à In 1887, the Sunshine State issued a series of regulations that required racial segregation in public transportation and other public facilities. By 1890, the South became fully segregated, meaning that blacks had to drink from different water fountains from whites, use different bathrooms from whites and sit apart from whites in movie theaters, restaurants, and buses. They also attended separate schools and lived in separate neighborhoods. Racial apartheid in the United States soon earned the nickname, Jim Crow. The moniker comes from a 19th-century minstrel song called ââ¬Å"Jump Jim Crow,â⬠popularized by a minstrel performer named Thomas ââ¬Å"Daddyâ⬠Rice, who appeared in blackface. The Black Codes, a set of laws Southern states began passing in 1865, after slaverys end, were a precursor to Jim Crow. The codes imposed curfews on blacks, required unemployed blacks to be jailed and mandated that they get white sponsors to live in town or passes from their employers, if they worked in agriculture. The Black Codes even made it difficult for African Americans to hold meetings of any kind, including church services. Blacks who violated these laws could be fined, jailed, if they could not pay the fines, or required to perform forced labor, just as they had while enslaved. Essentially, the codes recreated slavery-like conditions. Legislation such as the Civil Rights Act of 1866 and the Fourteenth and Fifteenth amendments sought to grant more liberties to African Americans. These laws, however, focused on citizenship and suffrage and did not prevent the enactment of Jim Crow laws years later. Segregation did not only function to keep society racially stratified but also resulted in homegrown terrorism against blacks. African Americans who did not obey Jim Crow laws could be beaten, jailed, maimed or lynched. But a black person neednt flout Jim Crow laws to become a target of violent white racism. Black people who carried themselves with dignity, thrived economically, pursued education, dared to exercise their right to vote or rejected the sexual advances of whites could all be targets of white racism. In fact, a black person neednt do anything at all to be victimized in this manner. If a white person simply didnt like the look of a black person, that African American could lose everything, including his life. Legal Challenges to Jim Crow The Supreme Court case Plessy v. Ferguson (1896) constituted the first major legal challenge to Jim Crow. The plaintiff in the case, Homer Plessy, a Louisiana Creole, was a shoemaker and activist who sat in a whites-only train car, for which he was arrested (as he and fellow activists planned). He fought his removal from the car all the way to the high court, which ultimately decided that separate but equal accommodations for blacks and whites werent discriminatory. Plessy, who died in 1925, would not live to see this ruling overturned by the landmark Supreme Court case Brown v. Board of Education (1954), which found that segregation was indeed discriminatory. Although this case focused on segregated schools, it led to the reversal of laws that enforced segregation in city parks, public beaches, public housing,à interstate and intrastate travel and elsewhere. Rosa Parks famously challenged racial segregation on city buses in Montgomery, Ala., when she refused to relinquish her seat to a white man on Dec. 1, 1955. Her arrest sparked the 381-day Montgomery Bus Boycott. While Parks challenged segregation on city buses, the activists known as the Freedom Riders challenged Jim Crow in interstate travel in 1961. Jim Crow Today Although racial segregation is illegal today, the United States continues to be a racially stratified society. Black and brown children are much more likely to attend schools with other black and brown children than they are with whites. Schools today are, in fact, more segregated than they were in the 1970s. Residential areas in the U.S. mostly remain segregated as well, and the high numbers of black men in prison mean that a large swathe of the African American population does not have its freedom and is disenfranchised, to boot. Scholar Michelle Alexander coined the term the New Jim Crow to describe this phenomenon.à Similarly, laws that target undocumented immigrants have led to the introduction of the term Juan Crow. Anti-immigrant bills passed in states such as California, Arizona,à and Alabama in recent decades have resulted in unauthorized immigrants living in the shadows, subject to shoddy working conditions, predatory landlords, a lack of healthcare, sexual assault, domestic violence and more. Although some of these laws have been struck down or largely gutted, their passage in various states have created a hostile climate that makes undocumented immigrants feel dehumanized. Jim Crow is a ghost of what it once was but racial divisions continue to characterize American life.
Wednesday, November 6, 2019
Godfather essays
Godfather essays Francis Ford Coppolas, award winning film, The Godfather portrays a mafia family trying to survive among a crumbling empire of crime. The Godfather is more then just a movie about dog-eat-dog. With the use of great camera shots, dialogue, acting, character development, and storyline Coppola was able to create a classic masterpiece. The agreement of criminality and family honor is achieved with perfect accuracy. The Godfather portrays themes such as power, violence, love and betrayal. Through these various themes Coppola creates a purpose, which allows the audience to identify with the Corleone family. The Godfather is for certain entertaining, but entertainment is not Coppolas main purpose in creating this film. Coppola displays a strong emphasis on family and family values. The Godfather is a story about a family and the importance of staying together. In the past traditional American families were stereotyped from television shows such as Leave it to Beaver and The Brady Bunch. These families hold the stay at home mom who cooks and cleans for her working husband and the children who may get into trouble, but seem all too perfect. As America continues to get older the stereotypical family seems harder to believe. The Godfather displays a family that some may view as dysfunctional, but through the plot one understands they hold true family values. For instance, the Don never wanted his son Michael in the family business but instead wanted him to have a respectable job. Through displaying a different natured family Coppola is able to create the image that family worth is not based on how perfect the family seems. The Corleone family is involved in a business of crime. However, Coppola balances the story between family life and the ugly business in which they are engaged. No matter how ugly or sinful the business gets the love and respect this family has within their h ...
Monday, November 4, 2019
Individual-based reflection paper(management) Essay
Types of Managers and Steps in Management - Essay Example These managers, in particular, are the ones who most of us are familiar with, as unless we are lucky enough to land a top job right away, we will be with these guys. If something comes up in the department, they are usually the first to know ââ¬â being in charge, they should be. As the title implies, a manager is expected to supervise - to manage ââ¬â his department and his subordinates. Specifically, he is expected to get things done efficiently (minimum cost, maximum output) and effectively (attaining goals and doing the right things). This means that it is highly desirable to attain oneââ¬â¢s goals while using the least possible amount of resources. This process is called management. The first step in management is to plan ââ¬â to set goals, come up with a strategy, and develop plans to coordinate abilities. This answers the questions of what you want, how you plan to get it, and what you will do to get it. The next step is to organize, that is, the manager then del egates tasks to his subordinates, decides how tasks are to be grouped and what needs to be done. In this step, it is important to take into account who is best suited to handle certain tasks. For instance, if your plan calls for the use of print ads, hire a graphic artist ââ¬â or better yet, find someone on the team who has talent in that area. This step is where a managerââ¬â¢s interpersonal skills are needed most. As he is expected to know his subordinates relatively well, this is an important decision one must take great caution in making ââ¬â and which one has absolutely no excuse for fumbling. Next would be to lead oneââ¬â¢s subordinates ââ¬â that is, to motivate them, direct them, choose an effective means of communication, and resolve conflicts should they arise. Finally, to control ââ¬â monitoring performance, comparing it with company goals, and making changes when necessary.Ã
Friday, November 1, 2019
WAN, Architecture Overview Research Paper Example | Topics and Well Written Essays - 1500 words
WAN, Architecture Overview - Research Paper Example regard, this proposal aims at coming with up a clear description of the different types WAN connections that can be integrated into an organization (DiMarzio, 2001). The term WAN (Wide Area Network) refers to a large-scale internet connection that exists over a huge geographical terrain and typically connects two or more Local Area Networks. It is usually made up of a significant number of interconnected devices such as hubs, multiport switches, routers and satellite dishes (DiMarzio, 2001). One of the key needs of the WAN architecture to an organization is to provide faster access to files. Most organizations face the challenge of having to reload files. This is usually experienced in slow network connection situations (Meyers, 2004). Consequently, this affects the ability of the organization to succeed in meeting its set out business goals. However, with the WAN it becomes easier to enjoy speedy access to organizational data (DiMarzio, 2001). The WAN architecture is also of great need particularly in effective management of remote organization offices. That is, the WAN provides an efficient platform for managing and sharing of data between multiple office locations. To be precise, adoption of WAN solutions maximize the organizational network speed between remote business offices and accelerates file transfer (Karris, 2009). Another indispensable need of the WAN architecture is the ability to reach the global customer base. With an all-time internet access, it facilitates maximal access to the targeted global customer group. That is, it makes it easy to reach a wide customer set of customers, which is crucial in promoting business continuity. It thus plays a huge in increasing profits and meeting the set out business goals (DiMarzio, 2001). Communication is always a crucial need for effective business operations. In this sense, adoption of the WAN architecture technology acts a key need specifically in improving optimal performance of key business
Subscribe to:
Posts (Atom)